u/Big-Entrepreneur9343

I cleared mission 14-16 (the trial of lake verity, valor, acuity) but accidentally beat Mesprit, Uxie, and Azelf without catching it... :( 

I went back to the caves and they are not there anymore... is it no longer possible to try and catch them again? Or do I have to finish the game (I'm on mission 20, "the researcher of myths") and will they spawn again?