u/Smooth-Month-277

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1.0 SUBSTRATE

Parameter Specification
Material Schott Borofloat 33 borosilicate glass
Dimensions 25.00 mm × 25.00 mm × 6.000 mm ±0.025 mm
Flatness <2 μm across full surface
Surface finish <5 nm Ra, both faces
Edge chamfer 0.20 mm × 45°, no chips >50 μm
Quantity 3 identical substrates

2.0 GRID LAYOUT

Parameter Specification
Grid type 4×4 Cartesian
Pitch 5.000 mm ±0.010 mm center-to-center
Origin (0,0) Bottom-left corner of substrate
Grid offset X 5.000 mm from left edge
Grid offset Y 5.000 mm from bottom edge
Cavity positions (X,Y) mm (0,0), (5,0), (10,0), (15,0) / (0,5), (5,5), (10,5), (15,5) / (0,10), (5,10), (10,10), (15,10) / (0,15), (5,15), (10,15), (15,15)

3.0 CAVITY ARCHETYPES

Parameter TYPE S (△) TYPE M (◼︎) TYPE L (▲)
Symbol ◼︎
Diameter 3.000 mm ±0.005 mm 2.000 mm ±0.005 mm 1.500 mm ±0.003 mm
Depth 5.000 mm ±0.010 mm 10.000 mm ±0.010 mm 20.000 mm ±0.010 mm
Aspect ratio 1.67:1 5:1 13.33:1
Volume 35.34 mm³ 31.42 mm³ 35.34 mm³
Time constant (τ) 0.50 s ±0.02 s 1.00 s ±0.03 s 2.30 s ±0.05 s
Wall angle 90° ±0.3° 90° ±0.3° 90° ±0.3°
Wall finish <0.1 μm Ra <0.1 μm Ra <0.1 μm Ra
Bottom finish <0.2 μm Ra <0.2 μm Ra <0.2 μm Ra
Corner radius <50 μm <50 μm <50 μm

4.0 CAVITY ASSIGNMENTS, CORE FFT (SPATIAL FREQUENCY DECOMPOSITION)

X (mm) Y (mm) Type τ (s)
0 15 L 2.30
5 15 M 1.00
10 15 S 0.50
15 15 S 0.50
0 10 M 1.00
5 10 L 2.30
10 10 M 1.00
15 10 S 0.50
0 5 S 0.50
5 5 M 1.00
10 5 L 2.30
15 5 M 1.00
0 0 S 0.50
5 0 S 0.50
10 0 M 1.00
15 0 L 2.30

Kernal type, Symmetric Hankel. Anti-diagonals constant. Sensitive to spatial frequencies. No directional preference..

5.0 CAVITY ASSIGNMENTS, CORE GX (X-AXIS GRADIENT)

X (mm) Y (mm) Type τ (s)
0 15 S 0.50
5 15 S 0.50
10 15 M 1.00
15 15 L 2.30
0 10 S 0.50
5 10 S 0.50
10 10 M 1.00
15 10 L 2.30
0 5 S 0.50
5 5 M 1.00
10 5 L 2.30
15 5 L 2.30
0 0 S 0.50
5 0 M 1.00
10 0 L 2.30
15 0 L 2.30

Gradient principle, Left columns (X=0,5) fast S-dominant, Right columns (X=10,15) slow L-dominant. Center transition M. Left heating → early output peak. Right heating → late output peak. Skewness proportional to ∂T/∂x,

6.0 CAVITY ASSIGNMENTS, CORE GY (Y-AXIS GRADIENT)

X (mm) Y (mm) Type τ (s)
0 15 L 2.30
5 15 L 2.30
10 15 M 1.00
15 15 S 0.50
0 10 L 2.30
5 10 L 2.30
10 10 M 1.00
15 10 S 0.50
0 5 L 2.30
5 5 M 1.00
10 5 S 0.50
15 5 S 0.50
0 0 M 1.00
5 0 M 1.00
10 0 S 0.50
15 0 S 0.50

Gradient principle, Top rows (Y=10,15) slow L-dominant. Bottom rows (Y=0,5) fast S-dominant. Middle transition M. Bottom heating → early output peak. Top heating → late output peak, Skewness proportional to ∂T/∂y..

7.0 UWA-1

Component Specification
Base Pharmaceutical-grade paraffin wax, Tm = 60.0°C ±0.1°C
Latent heat 185 J/g ±5 J/g
Dopant 1 Pristine MWCNTs, Ø10-30 nm, L:1-10 μm, unfunctionalized, >95% purity
Loading 1 2.00 wt% ±0.05 wt%
Dopant 2 n-Tetracontane (C₄₀H₈₂), >99% purity, Tm = 81.0°C ±0.5°C
Loading 2 0.50 wt% ±0.02 wt%
Thermal conductivity (solid) 0.45 W/m·K
Thermal conductivity (liquid) 0.38 W/m·K

7.1 Composite Preparation

Step Action Parameters
1 Melt paraffin 82°C ±2°C, argon atmosphere
2 Add MWCNTs High-shear 10,000 RPM, 30 min, 80-85°C
3 Add tetracontane 5,000 RPM, 15 min, 80°C
4 Ultrasonic probe 20 kHz, 100 W, pulse 5s/2s, 60 min, 78-82°C
5 Degas <1×10⁻² mbar, 80°C, 60 min, until bubble-free
6 Store Sealed, argon-filled, 6-month shelf life

8.0 INFUSION PROTOCOL

Step Action Parameters
1 Clean substrates IPA ultrasonic, 40°C, 15 min → DI water rinse → N₂ dry → vacuum oven 120°C, 2 hr
2 Preheat Substrate to 75°C ±1°C on vacuum hotplate
3 Evacuate <1×10⁻³ mbar, hold 2 hr at 75°C
4 Introduce UWA-1 Via heated manifold, 75°C, sufficient to cover all cavities + 2 mm
5 Backfill Argon to 2.0 bar absolute
6 Pressure hold 30 min at 2.0 bar, 75°C
7 Directional solidification Gradient 5°C/mm across substrate thickness. Cool 0.20°C/min ±0.02°C/min from 75°C to 25°C under 0.5 L/min argon flow
8 Inspect X-ray micro-CT, voxel <5 μm. Zero voids >0.01 mm³ in any cavity. Reject and rework if voids detected.

9.0 THERMAL BUSES

Parameter Specification
Material CVD single-crystal diamond
Dimensions 25.00 mm × 25.00 mm × 0.100 mm ±0.005 mm
Thermal conductivity &gt;1800 W/m·K
Electrical resistivity &gt;10¹² Ω·cm
Surface finish <1 nm Ra, both faces
Quantity per core 2 (top incident face, bottom observer face)

9.1 Bonding

Parameter Specification
Adhesive BNNT-filled epoxy, 5 wt% loading
Bond line thickness <5 μm
Thermal resistance <0.1°C/W
Cure 25°C, 24 hr, vacuum compression 0.5 MPa
Post-cure 60°C, 4 hr, no pressure

10.0 PYROELECTRIC OBSERVER

Parameter Specification
Material z-cut LiTaO₃, single crystal
Dimensions 25.00 mm × 25.00 mm × 0.100 mm ±0.005 mm
Pyroelectric coefficient &gt;2.0 × 10⁻⁴ C/m²·K
Relative permittivity 46 at 1 kHz
Surface finish <1 nm Ra

10.1 Electrodes

Parameter Specification
Adhesion layer Cr, 5 nm ±1 nm
Conductor Au, 100 nm ±10 nm
Bottom electrode Full-area ground plane, Z- face
Top electrodes 16 individual, aligned to cavities
Electrode sizes S: 3.2×3.2 mm, M: 2.2×2.2 mm, L: 1.7×1.7 mm
Alignment tolerance ±10 μm to cavity centerlines
Patterning Photolithography, lift-off
Edge pads 16 signal + 2 ground, 0.5×0.5 mm, 0.8 mm pitch

10.2 Poling

Step Parameters
Temperature 85°C ±1°C
Voltage 100 V DC (Z+ positive), field = 1 MV/m
Hold 30 min at 85°C
Cool 1°C/min to 25°C under field
Remove field At 25°C
Verify Pyroelectric coefficient >2.0 × 10⁻⁴ C/m²·K

11.0 ENCAPSULATION

Parameter Specification
Lid CVD diamond, 25×25×0.100 mm
Seal adhesive BNNT-filled epoxy, <10 μm bond line
Internal atmosphere argon, 6N purity, 1.10 bar absolute at 25°C
Getter Barium flash, 5×5 mm, activated post-seal
Leak rate <1×10⁻⁸ atm·cc/s helium

12.0 CALIBRATION/ TFP...

Step Action Parameters
1 Uniform step 25°C → 30°C in <0.1 s. Record 16 ch at 200 Hz for 10 s. Extract τ per cavity. Verify within ±15% of nominal. Extract sensitivity (mV/°C).
2 Gradient GX Left 30°C / Right 25°C. Record skewness. Calibration point +0.33°C/mm. Reverse for −0.33°C/mm. Fit linear model: ∂T/∂x = a·skewness + b.
3 Gradient GY Top 30°C / Bottom 25°C. Record skewness. Calibration point −0.33°C/mm. Reverse for +0.33°C/mm. Fit linear model: ∂T/∂y = a·skewness + b.
4 Frequency sweep FFT 0.1, 0.2, 0.5, 1.0, 2.0, 5.0 Hz sinusoidal modulation. Record 16×16 coupling matrix.

12.1 Personality Map

  • Core serial number and calibration date
  • τ per cavity (16 values)
  • Sensitivity per cavity (16 values)
  • GX skewness coefficients (a, b)
  • GY skewness coefficients (a, b)
  • FFT coupling matrix (16×16)
  • Thermal offset calibration

13.0 SYSTEM INTEGRATION

Parameter Specification
Configuration 3 cores (FFT, GX, GY) on common thermal stage
Stage Copper, Peltier-controlled, 25.0°C ±0.01°C
Spacing 10 mm between cores
Optics (optional) Ge lens, f/2, 50 mm FL, AR 8-14 μm, FOV 30°×30°
Flex circuit Polyimide, 18 μm Cu traces, 20-pin ZIF, 100 mm length, shielded
Readout 16-ch charge amplifier, 0.1-100 Hz BW, 200 Hz sample rate, 16-bit ADC

13.1 Output Vector

Quantity Source Units
Spatial frequency spectrum FFT Core (16 components) Normalized amplitude
∂T/∂x GX Core °C/mm
∂T/∂y GY Core °C/mm
∇T
θ (gradient direction) atan2(GY,GX) radians
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