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These moments are taken from:
- Sasuke Retrieval Arc
- Tenchi Bridge Reconnaissance Mission Arc
- Itachi Pursuit Mission Arc
- Pain's Assault Arc
- Fourth Shinobi War Arc
- Before and After the Second Final Valley Fight
There are still more moments from these and other arcs, but they are implied or need explanation.
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Explaining Pics (5): The foundation for feeling like real brothers/family started years before Team 7 because Naruto told Sasuke he saw him as his brother during the first Final Valley fight. Then Naruto said this bond was one of the first bonds he ever had, and it immediately cuts to them as young kids (both smiling) about five years before Team 7. And right before this reveal, child Naruto had an internal monologue discussing his orphan experience at that very young age and how he was connecting with the other orphan's suffering. Their shared extreme loneliness and trauma were the foundation for this family-like connection 5 years before Team 7, and Sasuke says the same after their final fight. Naruto was seeing the brother he never had in Sasuke, and Sasuke was filling the blood family he lost with Naruto, specifically the brother spot (Itachi) and seeing Itachi in Naruto.
Explaining Pics (6): Sasuke was clearly moved by Naruto’s seeing him as a real brother and started showing him respect for the first time in this fight. He put on his headband after that line, which had been a request from Naruto during their hospital rooftop fight: to put on his headband and fight him as an equal. Back then, Sasuke refused, saying, “You’re never my equal.” So here, Sasuke was acknowledging Naruto as an equal in both strength and loneliness, and he literally says that to him right after this scene. When Naruto asked why he would even bother with the headband when he still wanted to kill him, Sasuke said, “It's because you know what loneliness is, just like I do. Now we will fight as equals".