r/chemhelp

Assessing for least basic nitrogen

Assessing for least basic nitrogen

Hi Folks,

This was a question from our last exam, which I got correct but I was close to selecting letter A.

Here is my thinking:
The lone pairs on B and D are not contributing to aromaticity and are therefore free to act as a source of electrons, this makes them more basic so we can eliminate these two options. Same situation for option A I guess, right?

The lone pair on C is contributing to aromaticity on this molecule, and is less available as a source of electrons (less available to act as a base).

What if we compared A to C and asked which is more acidic? Would C be more acidic because the conjugate base has resonance stabilization and option A does not?

Okay, thanks for your help!

u/neko_pan — 10 hours ago

Synthesis Help Bond Disconnections Help

I’m very confused where the bond disconnections are I know it’s between N - H and C = 0 bonds but that’s only 2 and I have 4 fragments to find where’s the other ones in these Qs

u/LowBiscotti4996 — 10 hours ago
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Is There a Definitive Chemical Test to Tell Groundwater from Surface Water?

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u/Alilack — 17 hours ago

At what point in studying chemistry and its fundamentals should one start practicing chemical reactions hands-on?

Hello everyone!!

I don't come from a wealthy family; I'd even say we barely made ends meet, but we're not complaining much; we have internet, food, and so on.

The problem is, I'm afraid to start studying chemistry from the very beginning because of the practical requirements.

I'm inclined to believe that I simply won't have the funds for my own experiments, but I really want to start studying chemistry, and I understand that at some point I'll need to transition to practical applications, especially since that's why I originally went into chemistry.

Please tell me, should I wait, or should I still study all the theoretical material on chemistry and perfect my equations, or should I wait until I've settled on the money and start studying chemistry later?

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u/Sweet-Structure8633 — 1 day ago

Where to put workings in very small space per question

I am doing my summer work to go into AP Chemistry

I don’t want help with the problems and I already emailed my teachers about this but they are on summer break - where do I genuinely put my work to do the problem especially problems such as 9. as someone with large handwriting who shows a lot of work to avoid making mistakes. Should I attach a scrap paper and do my work there?

u/VanishedHound — 1 day ago

Chirality help

These two molecules baffle me. I can't tell where the hydrogens are pointing and what the orders of priority are.

Appreciate your help ⭐

Edit : My initial answers are S,S for both the molecules but the the book says otherwise so I kinda suspect if I get the orders of priority wrong here. I'm quite convinced that the hydrogens are pointing backwards

u/S1lhou3tte_ — 1 day ago

Asking for help with pinpointing chemical causing discoloration

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Which chemical/s are most likely to have caused this discoloration above? Asking for curiosity purposes. Also, is there a way to reverse the discoloration, preferably through affordable means? Thank you!

u/RandomaticPersonQ — 2 days ago

Diels Alder and Grignard reaction

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u/Lontra_furetto_31821 — 2 days ago

IUPAC Parent Chain Help!

Hey all!

As per the current IUPAC Blue Book, I see that a parent chain must have the most amount of heteroatoms. However, that leads to confusion here:

OCCC(=O)O

The highest priority would be the carboxylic acid, so the chain would be CCCO? But this doesn't make sense, as I know the chain would be CCC.

I am struggling to understand the heteroatom priority. Below is the exact rule as per the Blue Book.

>In an acyclic compound consisting of individual atoms, alike or
different (an acyclic chain), the chain on which the nomenclature and
numbering is based is called the ‘principal chain’. When there is a
choice for the principal chain, the following criteria are applied, in
the order listed, until a decision is reached.

The principal chain:

(a) contains the greater number of heteroatoms of any kind;

(b) has the greater number of skeletal atoms;

(c) contains the greater number of the most senior acyclic heteroatom in
the following sequence: O > S > Se > Te > N > P > As
> Sb > Bi > Si > Ge > Sn > Pb > B > Al > Ga
> In >Tl.

Am I right in assuming all thats needed is to ensure that the hetero atom isn't terminal, i.e. is between 2 carbons?

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u/Daggers_and_shoes — 2 days ago

Need advice on how to properly study for gen chem 2, I've been watching lectures, reading the textbook, and attempting problems but nothing sticks

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So in the example problem, I paused the video and attempted to do the problem. Since finding pH and were given titration and Molarity as well as Ka, i thought that we would just plug everything into the Henderson formula and get the pH (of course we would have to convert Ka to pKa). I did that and I got the answer wrong. I continued the video and saw that we actually had to make an ICE table and also had to recognize some rules regarding titration, which I had no idea about.

I hope someone has advice on what to do. I feel like the concepts don't stick, leading me to not know what to do in questions, making me panic and get them wrong. I feel like I treat it like bio class, which may be the reason why i struggle with it so much.

u/Thatonethrowaway384 — 2 days ago

I already answered these questions, but I need some clarification. I do not understand this stuff and I do not know how I can understand it. If someone could answer these and tell me why the answer is the answer, it would make my entire life.

Further clarification: this is not my homework, these are merely practice problems, I did not have homework on this stuff, so this is almost foreign. I can also upload pictures of my work if I need to

u/BackgroundVillage761 — 3 days ago

Resonance Curved Arrow Pushing

Does it matter how you draw your arrows when using curved arrows for resonance? For example, in this problem, I started the tails of my arrows in different places from the textbook's answer. Does either way suffice, or is it more "stable" or realistic to use the textbook's answer and why? Should you always choose the shortest path for arrows?

u/Choice-Plan-7559 — 3 days ago

Confusion on regioselectivity

i'm not sure if i misunderstand regioselective, but i think of it as a reaction producing multiple constitutional isomers with a major/minor product

however, the answer key says that because multiple acetonides can form, the reaction is neither regioselective or stereoselective.

isn't a defining part of regioselectivity having two products that are constitutional isomers?

(image 2 for acetonide group the question provided)

u/tungtungtung337 — 4 days ago

Retro & Forward synthesis help/confusion

My professor assigned additional problems to our lecture and I am completely stuck! His instructions were to “Use any resources needed to fill out the synthesis below. Any 3-carbon molecule may be used. Protecting groups may be necessary/included.” To begin I put my cut at C-N. Following that I identified the heteroatom as being two carbons away, meaning an epoxide was needed. I chose my three carbon material to be propylamine. Thus far is this correct? The trouble I was running into was forming the epoxide. Since there is no double bond present MCPBA isn’t an option at this point and Br2/H20 would add an additional alcohol to the already present OH. I have no idea where to go from here any help is appreciated!

u/No_Variation1284 — 4 days ago

Mechanism Help

Hi all, it’s been a few years since I’ve taken Orgo 1 and I’m doing a review assignment. Would someone mind walking me through the mechanism for this reaction?

u/Final-Oil2392 — 4 days ago