▲ 1 r/Vit

Guys what all is visible to you in freshers portal could someone update below

Guys what all is visible to you in freshers portal could someone update below

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u/Ok-Construction4497 — 6 days ago
▲ 8 r/Vit

When does the hostel dees and allocation prcess start for freshers and when is the orientation and date of start of classes further more if we want to with draw we will also get the hostel fees refunded right

When does the hostel dees and allocation prcess start for freshers and when is the orientation and date of start of classes further more if we want to with draw we will also get the hostel fees refunded right

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u/Ok-Construction4497 — 8 days ago

Guys I forgot to upload my class 12 marksheet during preference form filling

Guys I forgot to upload my class 12 marksheet during preference form filling please tell if I can upload in the future????

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u/Ok-Construction4497 — 10 days ago
▲ 2 r/Vit

Seniors do we pay for hostel at the vit vellore campus or in the freshers campus a month before

Seniors do we pay for hostel at the vit vellore campus or in the freshers portal a month before

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u/Ok-Construction4497 — 13 days ago

Regarding Internships at bits hyd

Could any seniors give me a timeline and process for internships of dual degree holders. I my understanding they dont have ps1 but have s1 and ps2 also what do these signify like what do these particular intenships entail like no pay etc???

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u/Ok-Construction4497 — 14 days ago

Regarding bits dual degree in bits hyd

So how stressfull is it and what percentage of stu get mnc or cse allotted. Also how many extra courses per sem for a dual degree student.

Please advise me on this seniors

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u/Ok-Construction4497 — 14 days ago

Regarding Dual Degrees at BITS HYD

Could you please clarify the dual-degree allotment process for MSc students? My understanding is that students can opt for a dual degree at the end of their second semester, with course availability being determined by their first-year CGPA. Is this correct?

Also Does anybody have branch cutoffs for BE allotment of last year in BITS Hyd Campus

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u/Ok-Construction4497 — 15 days ago

Guys 100 percent some kind of cheating happened this year because the data seems so anomalous and impossible

Guys 100 percent some kind of cheating happened this year because the data seems so anomalous and impossible

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u/Ok-Construction4497 — 16 days ago

Guys feel like mathongo ke ranges ke waja se 5 to 9 makrs increase hue hai from my friend it went from 170 to 179 in math ongo so after officail key sabke niche jayenge also i think the data has almost reached peak saturation

Guys feel like mathongo ke ranges ke waja se 5 to 9 makrs increase hue hai from my friend it went from 170 to 179 in math ongo so after officail key sabke niche jayenge also i think the data has almost reached peak saturation

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u/Ok-Construction4497 — 18 days ago

Guys stop fearmongering assuming that in reality 1.5 times more people are sitting in this rank range at 90 it still goes to 16614 also the data is skewed in the midrange as mostly students who are mid will check while toppers and people getting very less marks will not be checking take a chill 💊

Guys stop fearmongering assuming that in reality 1.5 times more people are sitting in this rank range at 90 it still goes to 16614 also the data is skewed in the midrange as mostly students who are mid will check while toppers and people getting very less marks will not be checking take a chill 💊

ALSO WE ARE HAVING 8864 STUDENTS ABOVE 100 SO EVEN IFF WE DOUBLE IT LOOKS LIKE 2025 but obviously it will not be double ad midrange data is skewed so take it as 1.5 to 1.7 about the nos of people above you

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u/Ok-Construction4497 — 19 days ago

Guys stop fearmongering assuming that in reality 1.5 times more people are sitting in this rank range at 90 it still goes to 16614 also the data is skewed in the midrange as mostly students who are mid will check while toppers and people getting very less marks will not be checking take a chill 💊

(5737+3016+1409+568+232+81+29+4)×1.5=16,614

u/Ok-Construction4497 — 19 days ago

Here is a list of important compound names. Try to draw the structures or find them yourself.

This list covers the most essential common names in organic chemistry, specifically those frequently used in identification tests, stoichiometry, and naming problems (like JEE, NEET, and Olympiads).

1. Organic Acids (Aliphatic)

These are crucial for stoichiometry problems involving neutralization and esterification.

Common Name IUPAC Name Formula Notes
Formic Acid Methanoic acid $ce{HCOOH}$ Reduces Tollens' reagent (unique for an acid).
Acetic Acid Ethanoic acid $ce{CH3COOH}$ Found in Vinegar.
Oxalic Acid Ethanedioic acid $ce{(COOH)2}$ Used in redox titrations with $ce{KMnO4}$.
Malonic Acid Propanedioic acid $ce{CH2(COOH)2}$ Forms a cyclic anhydride easily.
Succinic Acid Butanedioic acid $ce{(CH2)2(COOH)2}$ Key in the Krebs cycle.
Adipic Acid Hexanedioic acid $ce{(CH2)4(COOH)2}$ Monomer for Nylon-6,6.
Lactic Acid 2-Hydroxypropanoic acid $ce{CH3CH(OH)COOH}$ Found in sour milk; contains a chiral center.
Malic Acid Hydroxybutanedioic acid $ce{HOOC-CH(OH)-CH2-COOH}$ Found in apples.
Tartaric Acid 2,3-Dihydroxybutanedioic acid $ce{[CH(OH)COOH]2}$ Used in Fehling's solution (as Rochelle salt).
Citric Acid 2-hydroxypropane-1,2,3-tricarboxylic acid $ce{C6H8O7}$ A tricarboxylic acid found in citrus.

2. Phenols and Benzenediols

Commonly used in Ferric Chloride tests and Coupling reactions.

Common Name Description Structure
Phenol Carbolic acid $ce{C6H5OH}$
Catechol 1,2-Dihydroxybenzene Ortho-isomer
Resorcinol 1,3-Dihydroxybenzene Meta-isomer
Quinol (Hydroquinone) 1,4-Dihydroxybenzene Para-isomer (used as developer)
Pyrogallol 1,2,3-Trihydroxybenzene Absorbs alkaline oxygen.
Phloroglucinol 1,3,5-Trihydroxybenzene Used in testing lignin.
o-Cresol 2-Methylphenol Ortho-methyl phenol.
Picric Acid 2,4,6-Trinitrophenol Highly acidic despite no $ce{-COOH}$ group.

3. Aromatic Acids & Aldehydes

Crucial for Cannizzaro and Perkin reactions.

Common Name IUPAC/Description Formula/Structure
Benzaldehyde Benzenecarbaldehyde $ce{C6H5CHO}$
Salicylaldehyde 2-Hydroxybenzaldehyde Product of Reimer-Tiemann reaction.
Benzoic Acid Benzenecarboxylic acid $ce{C6H5COOH}$
Salicylic Acid 2-Hydroxybenzoic acid Precursor to Aspirin.
Phthalic Acid Benzene-1,2-dicarboxylic acid Ortho-isomer.
Isophthalic Acid Benzene-1,3-dicarboxylic acid Meta-isomer.
Terephthalic Acid Benzene-1,4-dicarboxylic acid Used in making Terylene/Dacron.
Cinnamic Acid 3-phenylprop-2-enoic acid $ce{C6H5-CH=CH-COOH}$

4. Unsaturated Compounds

Important for Ozonolysis and addition stoichiometry.

Common Name IUPAC Name Formula
Acrolein Prop-2-enal $ce{CH2=CH-CHO}$
Crotonaldehyde But-2-enal $ce{CH3-CH=CH-CHO}$
Vinyl Alcohol Ethenol $ce{CH2=CHOH}$ (Unstable, tautomerizes)
Allyl Alcohol Prop-2-en-1-ol $ce{CH2=CH-CH2OH}$
Maleic Acid cis-Butenedioic acid cis-isomer (forms anhydride easily).
Fumaric Acid trans-Butenedioic acid trans-isomer (high melting point).

5. Nitrogen-Containing Compounds

Used in Carbylamine and Hinsberg tests.

Common Name IUPAC/Description Notes
Aniline Benzenamine Primary aromatic amine.
Acetanilide N-phenylacetamide Used to protect aniline group.
Urea Aminoformamide $ce{NH2CONH2}$ (First synthesized organic compound).
Pyridine Azabenzene $ce{C5H5N}$ (Basic heterocyclic compound).
Pyrrole Azole 5-membered heterocyclic ring.
Glycine 2-aminoethanoic acid Simplest amino acid (not chiral).

6. Summary Mnemonic for Dicarboxylic Acids

To remember the sequence of $\ce{-(CH2)_n-}$ between the two $\ce{-COOH}$ groups: "Oh My Such Good Apple Pie"

  • Oxalic ($n=0$)
  • Malonic ($n=1$)
  • Succinic ($n=2$)
  • Glutaric ($n=3$)
  • Adipic ($n=4$)
  • Pimelic ($n=5$)

7. Important Hydrocarbons

  • Toluene: Methylbenzene
  • Xylene: Dimethylbenzene (o, m, p)
  • Mesitylene: 1,3,5-Trimethylbenzene
  • Cumene: Isopropylbenzene (used to make phenol)
  • Styrene: Phenylethylene ($\ce{C6H5CH=CH2}$)

https://maipdf.com/file/a44d38b646238e@pdf

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u/Ok-Construction4497 — 26 days ago

Based on AYJR, I have noticed that they have been asking stoichiometric questions based on number of moles in tollens and fellings test so I have prepared the following PDF for reference, which contains the stoichiometric ratios of different compounds.

Below is the exhaustive list of compounds that react with Tollens' and Fehling's reagents, including the necessary stoichiometry for calculations.

Comprehensive Table of Positive Respondents

Compound Class Specific Examples Tollens' (Ag Mirror) Fehling's (Red Ppt) Stoichiometry (Reactant : Ag or $Cu_2O$)
Aliphatic Aldehydes Formaldehyde, Ethanal (+) (+) 1 : 2 Ag / 1 : 1 $Cu_2O$
Aromatic Aldehydes Benzaldehyde (+) (-) 1 : 2 Ag
$alpha$-Hydroxy Ketones Fructose, Acetoin (+) (+) 1 : 2 Ag / 1 : 1 $Cu_2O$
Formic Acid $HCOOH$ (+) (+) 1 : 2 Ag / 1 : 1 $Cu_2O$
Reductones Ascorbic Acid (Vit C) (+) (+) 1 : 2 Ag / 1 : 1 $Cu_2O$
Hydrazines Phenylhydrazine (+) (+) 1 : 4 Ag / 1 : 2 $Cu_2O$
Hydroxylamines $R-NHOH$ (+) (+) 1 : 2 Ag / 1 : 1 $Cu_2O$
Polyhydroxy Phenols Hydroquinone, Catechol (+) (-) 1 : 2 Ag
Terminal Alkynes Ethyne, Propyne (+)* (-) 1 : 1 Ag-acetylide (Ppt)

Perfect Stoichiometric Equations for Calculations

1. Formic Acid ($HCOOH$)

Formic acid is the only carboxylic acid to give these tests because the Carbon-Hydrogen bond attached to the carboxyl group acts like an aldehyde.

  • Tollens': $HCOOH + 2[Ag(NH_3)_2]^(+) + 2OH^(-) \rightarrow CO_2 + 2Ag(s) + 4NH_3 + 2H_2O$
    • Ratio: $1 \text{ mol } HCOOH \rightarrow 2 \text{ mol } Ag$
  • Fehling's: $HCOOH + 2Cu^({2+}) + 4OH^(-) \rightarrow CO_2 + Cu_2O(s) + 3H_2O$
    • Ratio: $1 \text{ mol } HCOOH \rightarrow 1 \text{ mol } Cu_2O$

2. $\alpha$-Hydroxy Ketones ($R-CH(OH)-CO-R$)

These react because they undergo Lobry de Bruyn–van Alberda van Ekenstein transformation in the basic medium of the reagents to form aldehydes.

  • Equation: Treated effectively the same as aldehydes in calculations.
    • Ratio: $1 \text{ mol ketone} \rightarrow 2 \text{ mol } Ag$

3. Hydrazines ($NH_2NH_2$ or $R-NHNH_2$)

Hydrazines are very powerful reducing agents. Phenylhydrazine is often used in carbohydrate chemistry (Osazone formation) and will reduce Tollens' reagent to silver.

  • Tollens' (Hydrazine): $NH_2NH_2 + 4[Ag(NH_3)_2]^(+) + 4OH^(-) \rightarrow N_2 + 4Ag(s) + 8NH_3 + 4H_2O$
    • Ratio: 1 : 4 (Crucial for stoichiometry!)
  • Tollens' (Phenylhydrazine): $C_6H_5NHNH_2 + 2[Ag(NH_3)_2]^(+) + OH^(-) \rightarrow C_6H_6 + N_2 + 2Ag(s) + 4NH_3 + H_2O$
    • Ratio: 1 : 2

4. Hydroxylamines ($R-NHOH$)

  • Tollens': $R-NHOH + 2[Ag(NH_3)_2]^(+) + OH^(-) \rightarrow R-NO + 2Ag(s) + 4NH_3 + H_2O$
    • Ratio: $1 \text{ mol Hydroxylamine} \rightarrow 2 \text{ mol } Ag$

5. Polyhydroxy Phenols (Hydroquinone)

Used in photography as "developers" precisely because they reduce silver ions to metallic silver.

  • Equation: $C_6H_4(OH)_2 + 2[Ag(NH_3)_2]^(+) \rightarrow C_6H_4O_2 (\text{Quinone}) + 2Ag(s) + 2NH_4^(+) + 2NH_3$
    • Ratio: $1 \text{ mol Phenol} \rightarrow 2 \text{ mol } Ag$

6. Ascorbic Acid (Vitamin C / Reductones)

The enediol structure is highly sensitive to oxidation.

  • Equation: $C_6H_8O_6 + 2[Ag(NH_3)_2]^(+) \rightarrow C_6H_6O_6 (\text{Dehydroascorbic acid}) + 2Ag(s) + 2NH_4^(+) + 2NH_3$
    • Ratio: $1 \text{ mol Vitamin C} \rightarrow 2 \text{ mol } Ag$

Summary Checklist for Stoichiometric Analysis

If you are given a mass of "Silver Mirror" or "Red Precipitate" and asked to identify or quantify the organic compound:

  1. Ag : Organic = 2 : 1 $\rightarrow$ Standard Aldehyde, Aromatic Aldehyde, Formic Acid, $\alpha$-Hydroxy Ketone, or Hydroxylamine.
  2. Ag : Organic = 4 : 1 $\rightarrow$ Hydrazine ($N_2H_4$).
  3. $Cu_2O$ : Organic = 1 : 1 $\rightarrow$ Aliphatic Aldehyde or Formic Acid.
  4. $Cu_2O$ : Organic = 2 : 1 $\rightarrow$ Formaldehyde (if oxidized all the way to $CO_3^({2-}$) in excess reagent).

Note on $\alpha,\beta$-unsaturated ketones: If you encounter a problem where an unsaturated ketone gives a positive test, look closely at the structure. If it is an $\alpha,\beta$-unsaturated aldehyde (like Acrolein), it is (+). If it is a ketone with an $-\text{OH}$ group on the adjacent carbon, it is (+). Otherwise, simple ketones are consistently negative.

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u/Ok-Construction4497 — 26 days ago

So b/w vit vellore cat 2 cse and mu which is better for cse and job placements any suggestions guys Disregard roi What about mu scholarship as i have 96 percentile above in jee mains

So b/w vit vellore cat 2 cse and mu which is better for cse and job placements any suggestions guys

Disregard roi What about mu scholarship as i have 96 percentile above in jee mains

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u/Ok-Construction4497 — 27 days ago

20xx can someone guide me regd choice filling pls like can i get cse core cat 1 or only 2

20xx can someone guide me regd choice filling pls like can i get cse core cat 1 or only 2

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u/Ok-Construction4497 — 29 days ago