Trying to understand the chemistry of stainless steel corrosion by sodium hypochlorite

I am curious as to which specific chemical reactions and products occur during the process of corrosion of stainless steel by bleach. Stainless steel is a composite of Fe, Cr, and sometimes other metals such as Ni, and the outer layer of this composite is protected by a passivation layer of Cr2O3. If sodium hypochlorite is introduced, does it indiscriminately oxidize both the Fe and Cr, or is one kinetically favored over the other?

reddit.com
u/jun192022 — 15 hours ago

Trying to understand the chemistry of stainless steel corrosion by sodium hypochlorite

I am curious as to which specific chemical reactions and products occur during the process of corrosion of stainless steel by bleach. Stainless steel is an alloy of Fe, Cr, and sometimes other metals such as Ni, and the outer layer of this composite is protected by a passivation layer of Cr2O3. If sodium hypochlorite is introduced, does it indiscriminately oxidize both the Fe and Cr, or is one kinetically favored over the other?

reddit.com
u/jun192022 — 15 hours ago

Trying to understand the chemistry of stainless steel corrosion by sodium hypochlorite

I am curious as to which specific chemical reactions and products occur during the process of corrosion of stainless steel by bleach. Stainless steel is a composite of Fe, Cr, and sometimes other metals such as Ni, and the outer layer of this composite is protected by a passivation layer of Cr2O3. If sodium hypochlorite is introduced, does it indiscriminately oxidize both the Fe and Cr, or is one kinetically favored over the other?

reddit.com
u/jun192022 — 15 hours ago

Trying to understand the chemistry of stainless steel corrosion by sodium hypochlorite

I am curious as to which specific chemical reactions and products occur during the process of corrosion of stainless steel by bleach. Stainless steel is a composite of Fe, Cr, and sometimes other metals such as Ni, and the outer layer of this composite is protected by a passivation layer of Cr2O3. If sodium hypochlorite is introduced, does it indiscriminately oxidize both the Fe and Cr, or is one kinetically favored over the other?

reddit.com
u/jun192022 — 3 days ago

Trying to understand the chemistry of stainless steel corrosion by sodium hypochlorite

I am curious as to which specific chemical reactions and products occur during the process of corrosion of stainless steel by bleach. Stainless steel is a composite of Fe, Cr, and sometimes other metals such as Ni, and the outer layer of this composite is protected by a passivation layer of Cr2O3. If sodium hypochlorite is introduced, does it indiscriminately oxidize both the Fe and Cr, or is one kinetically favored over the other?

reddit.com
u/jun192022 — 3 days ago

Trying to understand the chemistry of stainless steel corrosion by sodium hypochlorite

I am curious as to which specific chemical reactions and products occur during the process of corrosion of stainless steel by bleach. Stainless steel is a composite of Fe, Cr, and sometimes other metals such as Ni, and the outer layer of this composite is protected by a passivation layer of Cr2O3. If sodium hypochlorite is introduced, does it indiscriminately oxidize both the Fe and Cr, or is one kinetically favored over the other?

reddit.com
u/jun192022 — 3 days ago

Trying to understand the chemistry of stainless steel corrosion by sodium hypochlorite

I am curious as to which specific chemical reactions and products occur during the process of corrosion of stainless steel by bleach. Stainless steel is a composite of Fe, Cr, and sometimes other metals such as Ni, and the outer layer of this composite is protected by a passivation layer of Cr2O3. If sodium hypochlorite is introduced, does it indiscriminately oxidize both the Fe and Cr, or is one kinetically favored over the other?

reddit.com
u/jun192022 — 3 days ago
▲ 5 r/WorkplaceSafety+3 crossposts

Unsure if I accidentally made carcinogenic hexavalent chromium by repeatedly applying bleach to stainless steel?

I have been applying a 2-3% bleach spray regularly to a stainless steel refrigerator door for disinfection every 1-2 days for the last 2-3 months and have noticed that there are areas of corrosion forming on the refrigerator door (I was not aware that you are not recommended to apply bleach to stainless steel, so please forgive my ignorance). I recently also noticed there is a powder forming below the refrigerator door from the bleach spray runoff, and that the powder has a slight yellowish tint.

I just learned that stainless steel contains the metal chromium, and that while the chemical form of chromium in stainless steel is harmless, there also exists a form called hexavalent chromium, which is carcinogenic. According to a webpage from the British Stainless Steel Association stating "There is one very specific example where corrosion [of stainless steel] may produce very small quantities of hexavalent chromium at ambient temperature. This is where some strong oxidisers with a pH of 10-14 are in prolonged contact with stainless steel and cause corrosion over time."

Given that bleach is an oxidizer, I am worried about whether these repeated bleach applications could have oxidized the stainless steel door enough to produce a significant amount of hexavalent chromium (which can be yellow, such as in the compound sodium chromate). In a situation like this, how likely is it that there is a harmful amount of hexavalent chromium produced from multiple dilute bleach applications to stainless steel?

u/jun192022 — 9 days ago

How stable is hexavalent chromium?

My understanding is that hexavalent chromium is a strong oxidant. If that is the case, why is hexavalent chromium pollution persistent in the environment? Wouldn't it quickly become reduced to the harmless trivalent form?

reddit.com
u/jun192022 — 10 days ago

How stable is hexavalent chromium?

My understanding is that hexavalent chromium is a strong oxidant. If that is the case, why is hexavalent chromium pollution persistent in the environment? Wouldn't it quickly become reduced to the harmless trivalent form?

reddit.com
u/jun192022 — 10 days ago

How stable is hexavalent chromium?

My understanding is that hexavalent chromium is a strong oxidant. If that is the case, why is hexavalent chromium pollution persistent in the environment? Wouldn't it quickly become reduced to the harmless trivalent form?

reddit.com
u/jun192022 — 10 days ago

Risk of Hexavalent Chromium Contamination from Applying Dilute Bleach Repeatedly to Stainless Steel?

I have been applying a 2-3% bleach spray regularly to a stainless steel refrigerator door for disinfection every 1-2 days for the last 2-3 months and have noticed that there are areas of corrosion forming on the refrigerator door (I was not aware that you are not recommended to apply bleach to stainless steel, so please forgive my ignorance). I recently also noticed there is a powder forming below the refrigerator door from the bleach spray runoff, and that the powder has a slight yellowish tint. I just learned that stainless steel contains chromium, and that while the chromium oxide in stainless steel contains trivalent chromium, I am wondering whether enough could have been oxidized such that a significant amount of hexavalent chromium could have been produced (which can be carcinogenic and which can be yellow, such as in sodium chromate). Theoretically, in a situation like this, how likely is it that there is a harmful amount of hexavalent chromium produced from multiple dilute bleach applications to stainless steel?

reddit.com
u/jun192022 — 17 days ago

Risk of Hexavalent Chromium Contamination from Applying Dilute Bleach Repeatedly to Stainless Steel?

I have been applying a 2-3% bleach spray regularly to a stainless steel refrigerator door for disinfection every 1-2 days for the last 2-3 months and have noticed that there are areas of corrosion forming on the refrigerator door (I was not aware that you are not recommended to apply bleach to stainless steel, so please forgive my ignorance). I recently also noticed there is a powder forming below the refrigerator door from the bleach spray runoff, and that the powder has a slight yellowish tint. I just learned that stainless steel contains chromium, and that while the chromium oxide in stainless steel contains trivalent chromium, I am wondering whether enough could have been oxidized such that a significant amount of hexavalent chromium could have been produced (which can be carcinogenic and which can be yellow, such as in sodium chromate).

reddit.com
u/jun192022 — 17 days ago

Risk of Hexavalent Chromium Contamination from Applying Dilute Bleach Repeatedly to Stainless Steel?

I have been applying a 2-3% bleach spray regularly to a stainless steel refrigerator door for disinfection every 1-2 days for the last 2-3 months and have noticed that there are areas of corrosion forming on the refrigerator door (I was not aware that you are not recommended to apply bleach to stainless steel, so please forgive my ignorance). I recently also noticed there is a powder forming below the refrigerator door from the bleach spray runoff, and that the powder has a slight yellowish tint. I just learned that stainless steel contains chromium, and that while the chromium oxide in stainless steel contains trivalent chromium, I am wondering whether enough could have been oxidized such that a significant amount of hexavalent chromium could have been produced (which can be carcinogenic and which can be yellow, such as in sodium chromate). Theoretically, in a situation like this, how likely is it that there is a harmful amount of hexavalent chromium produced from multiple dilute bleach applications to stainless steel?

reddit.com
u/jun192022 — 17 days ago

Risk of Hexavalent Chromium Contamination from Applying Dilute Bleach Repeatedly to Stainless Steel?

I have been applying a 2-3% bleach spray regularly to a stainless steel refrigerator door for disinfection every 1-2 days for the last 2-3 months and have noticed that there are areas of corrosion forming on the refrigerator door (I was not aware that you are not recommended to apply bleach to stainless steel, so please forgive my ignorance). I recently also noticed there is a powder forming below the refrigerator door from the bleach spray runoff, and that the powder has a slight yellowish tint. I just learned that stainless steel contains chromium, and that while the chromium oxide in stainless steel contains trivalent chromium, I am wondering whether enough could have been oxidized such that a significant amount of hexavalent chromium could have been produced (which can be carcinogenic and which can be yellow, such as in sodium chromate). Theoretically, in a situation like this, how likely is it that there is a harmful amount of hexavalent chromium produced from multiple dilute bleach applications to stainless steel?

reddit.com
u/jun192022 — 17 days ago

How much of a chemical hazard do car tire additives pose in everyday life?

I've recently come across a number of articles which suggest that car tires (and items made from recycled car tires, such as crumb rubber) may present a chemical hazard at various points throughout the tire lifespan:

Given that rubber is a polymer, my understanding is that theoretically, chemicals added to the car tire would probably be bound to the rubber matrix. However, I am unclear whether these would be covalently bound or not. I have the following questions:

  1. How securely are the chemicals in car tires bound to the rubber matrix?
  2. From a day-to-day perspective, if you were to touch an intact car tire, would the amount of these chemicals you might get on your skin or clothing or other items pose a health or safety concern?
u/jun192022 — 2 months ago

Is it safe for pest control techs to handle resident belongings with unchanged gloves?

I live in a large apartment complex, and recently a pest control technician came for a pest inspection service. I noticed that they came in wearing a pair of reusable black leather gloves and touched some items in my apartment while wearing the gloves. They also used those gloves to carry a satchel bag which appeared to have cans of pesticides (maybe some kind of bug spray?), but they did not apply any of those pesticides during the visit.

I am unfamiliar with pest control service practices and do not know if the technician had worn those gloves when applying pesticides elsewhere, so I am wondering - is this safe (any concerns for potentially getting pesticides on my belongings), and is this a common practice?

reddit.com
u/jun192022 — 2 months ago

How much of a chemical hazard do car tires pose in everyday life?

I've recently come across a number of articles which suggest that car tires (and items made from recycled car tires, such as crumb rubber) may present a chemical hazard at various points throughout the tire lifespan:

Given that rubber is a polymer, my understanding is that theoretically, chemicals added to the car tire would probably be bound to the rubber matrix. However, I am unclear whether these would be covalently bound or not. I have the following questions:

  • How securely are the chemicals in car tires bound to the rubber matrix?
  • From a day-to-day perspective, if you were to touch an intact car tire, would the amount of these chemicals you might get on your skin or clothing or other items pose a health or safety concern?
reddit.com
u/jun192022 — 2 months ago

How much of a chemical hazard do car tires pose in everyday life?

I've recently come across a number of articles which suggest that car tires (and items made from recycled car tires, such as crumb rubber) may present a chemical hazard at various points throughout the tire lifespan:

Given that rubber is a polymer, my understanding is that theoretically, chemicals added to the car tire would probably be bound to the rubber matrix. However, I am unclear whether these would be covalently bound or not. I have the following questions:

  • How securely are the chemicals in car tires bound to the rubber matrix?
  • From a day-to-day perspective, if you were to touch an intact car tire, would the amount of these chemicals you might get on your skin or clothing or other items pose a health or safety concern?
reddit.com
u/jun192022 — 2 months ago