I really enjoy when they talk about the more technical side of film making.
I re-watched the "Best of the Worst: New Releases" episode and they briefly discuss different aspects of film making through out. I just find it really interesting when they talk about what not to do, why things are done a certain way, how a scene can be improved and even re-editing a scene as an example. I'm just a regular movie enjoyer but all these tidbits make me appreciate the process more. Let me know of some other episodes i might have forgotten about to check out.